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团队简介
Team Introduction
课题组由1位教授(博导、硕导),3位副教授(硕导),以及多名实验员组成,师资力量强,实验设备完善。
课题组负责人汪宝和教授任石化中心科研一室主任,是教育部绿色合成及转化重点实验室重要成员之一,先后承担了多项国家自然科学基金项目和省部级、企业研究项目。
承担的纵向项目
(1)国家自然基金项目:具有一定疏水程度催化剂制备、表征及其在烯醛氧化反应 中的活性及作用机理研究
(2)国家自然基金项目:醋酸体系汽液相平衡的分子模拟研究
(3)国家自然基金项目:含钛介孔碳催化剂的可控合成及催化丙烯环氧化的构效关系研究
(4)中石化总公司:功能化介孔碳可控合成及微观构效机理研究
(5)国家863项目子课题“秸秆糖高压氢化裂解及生物化工醇精馏分离工艺技术研究”
承担的横向项目
(1)乙烯法甲基丙烯酸酯关键技术开发 中石油
(2)30万吨/年HPPO废水回收醇醚工艺包开发 中石化
(3)丙交酯合成纤维级聚乳酸关键技术实验研究 中国昆仑公司
(4)年产10万吨甘油连续生产装置技术开发 淮安骏亚油脂科技有限公司
(5)从HPPO装置废水中回收丙二醇单甲醚工艺技术开发 吉神化学
(6)10万吨/年葡萄糖裂解生产多元醇工艺 郸城财鑫糖业有限责任公司
(7)苯加氢法合成环己酮绿色新工艺开发 石家庄市矿区煤炭营销中心
(8)丙二醇异甲醚及丙二醇回收系统优化及技术改进 吉神化学工业有限公司
(9)废水中有机物回收工艺技术 岳阳群泰化工科技开发有限责任公司
(10)年产600吨抗氧剂B-215技术开发 威海文登市三晶化学有限公司
(11)油脂副产物生产脂肪酸甲酯,VE,甾醇项目 中粮天科生物工程有限公司
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支持扩展名:.rar .zip .doc .docx .pdf .jpg .png .jpeg授权专利:
[1] 从秸秆糖加氢裂解产物中回收甲醇和乙醇的装置及方法,汪宝和、朱璟、陈爽、魏东炜、田红兵,CN201610651163.5
[2] 一种连续纯化粗甘油的方法,汪宝和、朱璟、魏东炜、田红兵、陈爽,CN201610662963.7
[3] 一种从废水中回收有机物的节能减排方法,汪宝和、毕文波、魏东炜、胡接伏、朱璟、田红兵,CN201410228720.3
[4] 用于一步氧化酯化生产甲基丙烯酸甲酯的疏水催化剂及制备方法,汪宝和、朱璟、陈爽、尹金柱、魏东炜、田红兵,CN201310755293.x
[5] 从丙烯环氧化反应废水中回收有机物的热耦合节能系统及操作方法,汪宝和、周海廷、魏东炜、王来顺、田红兵、邵树清、朱璟,CN201310327399.X
[6] 利用热耦合连续制备天然维生素E及植物甾醇的系统及方法,汪宝和、魏东炜、田红兵、殷金柱、朱璟,CN201210231841.4
[7] 一种环己烯水合制备环己醇的方法,汪宝和、董广昌、魏东炜、朱璟、田红兵、殷金柱,CN201110061585.4
[8] 一种苯部分加氢制备环己烯的催化剂回收方法,汪宝和、董广昌、魏东炜、田红兵、朱璟、殷金柱,CN201110047202.8
代表性文章:
[1] Baohe Wang, HongxiaLiu, Yan Nie, Qiaoyun Qin, Jing Ma*. Insight into the effect of promoter Pb inPb-Pd catalyst on methyl methacrylate formation via direct oxidativeesterification: A DFT study[J]. Applied Surface Science, 2020, 510: 145320.
[2] Jing Ma,Xueqing Yang, Yutong Wang, Baohe Wang*. Electronic-level insight into the weakinteractions of ion pairs in acetate anion-based ionic liquids[J]. Journal ofMolecular Liquids, 2020, 303: 112668.
[3] Dongwei Wei,Mengying Li, Jing Ma, Baohe Wang*. Excess molar volumes of cyclohexanone withn-, sec-, or tert-butylbenzene: Application of the PFP theory andgraph-theoretical approach[J]. The Journal of Chemical Thermodynamics, 2020,143: 106050.
[4] Hongxia Liu,Jing Ma, Dongwei Wei, Baohe Wang*, JingZhu. Insight into the effect of Pd andPd3Pb surface structure on activation of reactant O2 and product H2O in directoxidative esterification[J]. Applied Surface Science, 2020, 500: 143852.
[5] Baohe Wang, Xinlei Cai, Liang Lu, Jing Ma*. A combination of low‐temperature reactiveand extractive distillation for methoxy‐2‐propyl acetate synthesis andseparation process: simulations and experiments[J]. Journal of ChemicalTechnology & Biotechnology, 2019, 94(10): 3292-3304.
[6] Baohe Wang, Huanhuan Han, Baomin Ge, Jing Ma, Jing Zhu, Shuang Chen*. An efficienthydrophobic modification of TS-1 and its application in the epoxidation ofpropylene[J]. New Journal of Chemistry, 2019, 43(26): 10390-10397.
[7] Baohe Wang, Liang Lu, Baomin Ge, Shuang Chen*, Jing Zhu, Dongwei Wei. Hydrophobic andhierarchical modification of TS-1 and application for propylene epoxidation[J].Journal of porous materials, 2019, 26(1):227-237.
[8] Jing Ma,Yan Nie, Baohe Wang*. Simulation study on the relationship between thecrosslinking degree and structure, hydrophobic behavior for poly(styrene-co-divinylbenzene) copolymer[J]. Journal of Molecular Structure, 2018,1173: 120-127.
[9] 王品品, 陈爽,董金诗, 汪宝和*. H1020树脂吸附糖精的动力学和热力学研究[J]. 化学工业与工程, 2018, 035(001):75-79.
[10] Baohe Wang, Baomin Ge, Jing Zhu*, Lina Wang. Process optimization study on thecarbonylation of methyl acetate[J]. Chinese Journal of Chemical Engineering,2018, 26(9): 1937-1942.
[11] Jing Ma,Baohe Wang, JingZhu. Construction of force field of acetic acidsystem[C]//ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 1155 16TH ST,NW, WASHINGTON, DC 20036 USA: AMER CHEMICAL SOC, 2018, 256.
[12] Jing Ma, Xueqing Yang, Yan Nie, Baohe Wang*. The influence of a hydrophobic carrier,reactant and product during H2O adsorption on Pd surface for the oxidativeesterification of methacrolein to methyl methacrylate[J]. Physical ChemistryChemical Physics, 2018, 20(15): 9965-9974.
[13] Baohe Wang,Yan Nie, Jing Ma*. The effect of bioadhesive on the interfacial compatibilityand pervaporation performance of composite membranes by MD and GCMCsimulation[J]. Journal of Molecular Graphics and Modelling, 2018, 80: 113-120.
[14] Baohe Wang, Mingjie Rong, Jing Zhu, Shuang Chen*, Dongwei Wei. Isobaric Vapor–LiquidEquilibria for (Water+ 1-Methoxy-2-propanol),(Water+ 2-Methoxy-1-propanol), and(1-Methoxy-2-propanol+ 2-Methoxy-1-propanol) at 101.3 kPa[J]. Journal ofChemical & Engineering Data, 2017, 62(4): 1341-1347.
[15] Baohe Wang, Mingjie Rong, Pinpin Wang, Shuang Chen*. Liquid–liquid equilibria for theternary system n-butyl acetate+ pyrocatechol+ water at different temperaturesat 101.3 kPa[J]. Journal of Chemical & Engineering Data, 2016, 61(9):3184-3189.
[16] Kangli You, Baohe Wang, Shuang Chen*, Dongwei Wei*. Measurement and Correlation of theSolubility of Antioxidant 626 in Alcohols[J]. Journal of Chemical &Engineering Data, 2016, 61(3): 1205-1209.
[17] Baohe Wang, Peiqian Zhang, Qiming Lu, Shuang Chen*, Jing Zhua, Wenjie Luo. Thetechnology of straw sugar conversion to diol chemicals[J]. Rsc Advances, 2016,6(68):63525-63531.
[18] Baohe Wang,Jinshi Dong, Shuang Chen, Lili Wang, Jing Zhu*. ZnCl2-modified ion exchangeresin as an efficient catalyst for the bisphenol-A production[J]. ChineseChemical Letters, 2014, 25(11): 1423-1427.
[19] Dongwei Wei*, Sainan Han, Baohe Wang. Excess molar enthalpies for binary mixtures ofcyclopentanone, cyclohexanone, or cycloheptanone with n-nonane at T= 298.15 Kand atmospheric pressure[J]. The Journal of Chemical Thermodynamics, 2014, 76:87-92.
[20] Dongwei Wei*, Sainan Han, Baohe Wang. Solid–liquid phase equilibrium study of binarymixtures of n-octadecane with capric, and lauric acid as phase change materials(PCMs)[J]. Fluid Phase Equilibria, 2014, 373: 84-88.
[21] Baohe Wang*, Hao Sun, Jing Zhu, Lili Wang, Shuang Chen. Bis (2‐mercapto‐ethyl) aminemodification of macroporous sulfonic resin catalyst in bisphenol‐asynthesis[J]. AIChE Journal, 2013, 59(10): 3816-3823.
[22] Baohe Wang*, Weili Ran, Wenjuan Sun, and Kun Wang. Direct oxidative esterification ofaldehyde with alcohol to ester over Pd/styrene-divinyl benzene copolymercatalyst[J]. Industrial & engineering chemistry research, 2012, 51(10):3932-3938.
[23] Baohe Wang, Lili Wang, Jing Zhu*, Shuang Chen, Hao Sun. Condensation of phenol andacetone on a modified macroreticular ion exchange resin catalyst[J]. Frontiersof Chemical Science and Engineering, 2013, 7(2): 218-225.
[24] Jing Zhu,Baohe Wang *, Dongzhi Liu. Synthesis of 1, 2-diiodotetrafluoroethane withpyrolysis gas of waste polytetrafluoroethylene as raw material[J]. GreenChemistry, 2013, 15(4): 1042-1047.
[25] Baohe Wang*, Weili Ran, Yanan Li, Jianping Xiong, Shaoyuan Li. Ternary and QuaternaryLiquid–Liquid Equilibria for Systems of Water+ Methanol+ Methylanthranilate+Toluene at Different Temperatures[J]. Journal of Chemical & EngineeringData, 2012, 57(12): 3309-3314.
[26] Baohe Wang*,Weili Ran, Wenjuan Sun, Kun Wang. Direct Oxidative Esterification of Aldehydewith Alcohol to Ester over Pd/Styrene-Divinyl Benzene Copolymer Catalyst,Industrial and Engineering Chemistry Research, 2012, 51(10):3932-3938.
[27] Baohe Wang*,Wenjuan Sun, Jing Zhu, Weili Ran, Shuang Chen. Pd-Pb/SDB Bimetallic Catalystsfor The Direct Oxidative Esterification of Methacrolein to Methyl Methacrylate,Industrial and Engineering Chemistry Research, 2012, 51(46): 15004-15010.
[28] Baohe Wang,Hui Li, Jing Zhu*, Wenjuan Sun, Shuang Chen. Prepareration and Charaterizationof mono-/multi-metallic hydrophobic catalysts for the oxidative esterificationof methacrolein to methyl methacrylate, Journal of Molecular Catalysis A:Chemical, 2013, 379(15): 322-326.
[29] Baohe Wang*,Weili Ran. An Overview of Hydrophobic Catalyst over Styrene-DivinylbenzeneCopolyme, Chemical Engineering Communications, 2012, 199(10):1236-1250.
汪宝和: wangbh@tju.edu.cn
马静:majing0027@tju.edu.cn
天津大学研究生院招生办公室
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